Kinetics, equilibrium, and mechanisms of sorption and desorption of 17α-ethinyl estradiol in two natural soils and their organic fractions.

Abstract A study was conducted on the kinetics, equilibrium, and mechanisms of sorption and desorption of 17α-ethinyl estradiol (EE2) in six sorbents, which were two natural soils (Bulk1 and Bulk2) and their fractions obtained by alkaline extraction, namely, humic acids (HA1 and HA2), and mineral-bond humins (MHU1 and MHU2). These sorbents, characterized by total organic carbon (TOC), black carbon (BC), gas adsorption and Fourier transform infrared spectra, were shown to be porous solids containing aromatic (hard carbon) and aliphatic carbon (soft carbon). The two-compartment first-order model fitted the kinetics of sorption very well (R 2  > 0.990). The fast and slow sorption rate constants ranged from 1.110 h − 1 and 0.026 h − 1 to 2.063 h − 1 and 0.067 h − 1 , respectively. The slow sorption was attributed to the diffusion of EE2 in micropores rather than organic matter. The Freundlich model fitted the equilibrium of sorption and desorption very well. The nonlinearity of sorption took the order MHU > bulk soil > HA and was positively related to BC/TOC (p