Tetra-O-4-methyl­phenyl­sulfonyl­penta­erythritol

2008 
In the title mol­ecule (systematic name: methane­tetra­yltetra­methyl­ene tetra-p-toluene­sulfonate), C33H36O12S4, the central C atom and the S atoms exhibit distorted tetra­hedral configurations. The aromatic rings in opposite arms are nearly parallel to each other, with a dihedral angle of 10.26 (8) or 3.45 (9)°. The mol­ecules are linked into a two-dimensional network parallel to the bc plane by weak C—H⋯O hydrogen bonds, π–π [centroid–centroid distance = 3.5806 (12) A] and S—O⋯π [O⋯centroid = 3.1455 (15) A and S—O⋯centroid = 122.41 (7)°] inter­molecular inter­actions. Intramolecular C—H⋯O hydrogen bonds are also present.
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