Asymmetric epoxidation of N-enoylsultams with urea-hydrogen peroxide/trifluoroacetic anhydride

2005 
Diastereomeric isomers of epoxides 15-28 are obtained in high yield and moderate to high optical purity when N-enoylsultams 1-14 incorporating a variety of chiral sultams as the chiral induction elements are treated with urea-hydrogen peroxide/trifluoroacetic anhydride.
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