Synthesis of Z-scheme g-C3N4/PPy/Bi2WO6 composite with enhanced visible-light photocatalytic performance

Abstract An all-solid-state Z-scheme photocatalytic system g-C 3 N 4 /PPy/Bi 2 WO 6 (GPB) is successfully fabricated by introducing both polypyrrole (PPy) and graphitic carbon nitride (g-C 3 N 4 ) nanoparticles on the surface of Bi 2 WO 6 microflowers. PPy, as a kind of conductive polymers, can be regarded as the Ohmic contact in Z-scheme systems. Furthermore, PPy serves as a charge transmission bridge between the g-C 3 N 4 and the Bi 2 WO 6 . The g-C 3 N 4 /PPy/Bi 2 WO 6 sample with the PPy amount of 0.5 wt% (GPB-0.5) exhibits enhanced visible-light absorption and high electron-hole separation efficiency. It can remove 98.0% of RhB within 100 min, the photocatalytic activity of which is higher than that of other control samples. Both photoelectrochemical test and scavenging experiment identify that h + and ⋅ O 2 − are the main active species in the photocatalysis process. Our work could offer a new sight to design and fabricate photocatalyst with excellent utilization efficiency of solar energy.