PIFA-mediated dearomatizative spirocyclization of phenolic biarylic ketones via oxidation and C-C bond cleavage.

Guihua Zhao,Biqing Li,Shuangshuang Wang,Man Liu,Yuan Chen,Bin Wang

PIFA-mediated dearomatizative spirocyclization of phenolic biarylic ketones via oxidation and C-C bond cleavage.

2020

Guihua Zhao
Biqing Li
Shuangshuang Wang
Man Liu
Yuan Chen
Bin Wang

The dearomatizing spirocyclization of phenolic biarylic ketones using PhI(OCOCF3)2 as oxidant is presented. The reaction affords various cyclohexadienones through C-C bond cleavage under mild condi...

Keywords:

Bond cleavage
Chemistry
Organic chemistry

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