(E,E)-4,4′-Dichloro-2,2′-(1,1′-azinodiethylene)diphenol
2007
The title compound, C16H14Cl2N2O2, was synthesized by the reaction of 1-(5-chloro-2-hydroxyphenyl)ethanone with hydrazine hydrate. The molecule sits on a crystallographic center of symmetry at the mid-point of the central N—N bond and both N atoms are acceptors in an intramolecular hydrogen bond. In the crystal structure, the planar molecules are arranged in a sheet-like motif with one C—H⋯O bond linking molecules within the sheets and a second C—H⋯O interaction between neighboring sheets. There is also a close Cl⋯Cl intermolecular approach of 3.54 (1) A within the sheets.
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