Reactive groups on polymer coated electrodes, 8. Novel conducting polymer interfaces produced by electrochemical copolymerization of functionalized thiophene activated esters with 3-methylthiophene

With the synthesis of two new functionalized thiophene activated esters and their electrocopolymerization with 3-methylthiophene, two types of redox active polymers have been prepared. FTIR studies of the resultant polymers reveal that both types of activated ester groups withstand the applied electrooxidative conditions and are correctly integrated into the corresponding polymers. The electrocopolymerization experiments show that the composition of the obtained polymers strongly depends on the ratio of the components in the reaction medium. With the increase of the ratios of pentafluorophenyl thiophene-3-acetate/3-methylthiophene or succinimido thiophene-3-acetate/3-methylthiophene, a higher concentration of functionalized thiophene units is incorporated into the polymer chains. The measurement of the conductivity on these polymeric films gave a value in the range of 10 -3 to 10 -2 S.cm -1 , which is comparable to that of the unsubstituted polythiophene and consistent with the conjugation grade suggested by electrochemical and UV-vis spectroscopic data. As expected, the pendant reactive ester groups on the electrode surfaces react rapidly with different amino compounds without loss of the electroactivity of the polymers. Therefore, these novel polymeric materials can be used as electrode interfaces for further functionalizations, especially for the immobilization of amines, peptides, and enzymes.