Iodine‐Mediated Direct Generation of o‐Quinone Methides at Room Temperature: A Facile Protocol for the Synthesis of ortho‐Hydroxybenzyl Thioethers

: An iodine-mediated preparation of ortho-quinone methides (o-QMs) from ortho-hydroxybenzyl alcohols by a C-O bond scission strategy is described. The in situ generated o-QMs were then employed for C-S bond formation by thio-Michael addition of thiols to provide the ortho-hydroxybenzyl thioethers (o-HBT) in moderate to excellent yields.