Using N-Tosylhydrazone as a Double Nucleophile in the Palladium-Catalyzed Cross-Coupling Reaction To Synthesize Allylic Sulfones

Without extra addition of sulfinate salt, allylic sulfones were synthesized by palladium-catalyzed cross-coupling of aryl iodide with N-tosylhydrazone. In this transformation, not only the diazo compound but also the sulfinate salt, which were both generated in situ from base-mediated decomposition of the N-tosylhydrazone, was used as nucleophilic partner.