cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate

2009 
The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo­[3.3.1]non-1-ylmeth­yl)­amine-κN]platinum(II) N,N-dimethyl­formamide solvate}, [PtCl2(C11H19N)2]·C3H7NO, consists of two metrically similar Pt complexes and two dimethyl­formamide solvent mol­ecules. Each PtII center is coordinated by the amine groups of two (1-adamantylmeth­yl)amine ligands and two Cl atoms in a cis-square-planar arrangement. The PtII centers lie slightly outside [0.031 (4) and 0.038 (4) A] the coordination planes. The N—Pt—N and Cl—Pt—Cl angles [92.1 (4)–92.30 (11)°] are slightly more open than the N—Pt—Cl angles [87.3 (3)–88.3 (3)°]. N—H⋯O and N—H⋯Cl inter­molecular hydrogen bonds are observed, forming two discrete pairs of complexes and solvent mol­ecules.
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