First complexes of diphenylphosphorylalkanones with titanium tetrafluoride

E. G. Il'in,A. S. Parshakov,V. G. Yarzhemskii,V. V. Danilov,G. V. Bodrin,E. I. Goryunov,E. E. Nifant’ev

First complexes of diphenylphosphorylalkanones with titanium tetrafluoride

2015

E. G. Il'in
A. S. Parshakov
V. G. Yarzhemskii
V. V. Danilov
G. V. Bodrin
E. I. Goryunov
E. E. Nifant’ev

The reaction of TiF4 with a twofold excess of Ph2P(O)CH2C(O)Me (L) (one of the simplest and, very likely, most practically interesting representatives of a new class of organophosphorus ligands—diorganylphosphorylalkanones) in CH2Cl2 has been studied.

Keywords:

Organic chemistry
Linkage isomerism
Chemistry
Inorganic chemistry
Fluorine
Titanium tetrafluoride

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