Mechanism for the formation of Poly(phenylsilsesquioxane)
2004
Poly(phenylsilsesquioxane) with molecular weight of 1400 was synthesized by hydrolysis of phenyltrichlorosilane, followed by condensation of the resulting hydrolyzates in the presence of a catalytic amount of hydrochloric acid in methyl isobutyl ketone. The progress of dehydration of the hydrolyzates leading to poly(phenylsilsesquioxane) was monitored by 29 Si NMR spectroscopy. Dehydration of cis-(1,3,5,7-tetrahydroxy)-1,3,5,7-tetraphenylcyclooctasiloxane as a model compound was also investigated by the 29 Si NMR technique. The mechanism for the formation of poly(phenylsilsesquioxane) is discussed.
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