Palladium-catalyzed double carbonylation of aryl halides to give .alpha.-keto amides. Mechanistic studies

Fumiyuki Ozawa,Hidehiko Soyama,Hisayoshi Yanagihara,Issei Aoyama,Hiroaki Takino,Kunisuke Izawa,Takakazu Yamamoto,Akio Yamamoto

Palladium-catalyzed double carbonylation of aryl halides to give .alpha.-keto amides. Mechanistic studies

1985

Fumiyuki Ozawa
Hidehiko Soyama
Hisayoshi Yanagihara
Issei Aoyama
Hiroaki Takino
Kunisuke Izawa
Takakazu Yamamoto
Akio Yamamoto

Divers halogenures d'aryles sont convertis catalytiquement en α-cetoamides et amides par traitement avec des amines secondaires et le monoxyde de carbone

Keywords:

Nuclear magnetic resonance spectroscopy
Halide
Aryl
Carbon monoxide
Carbonylation
Catalysis
Palladium
Organic chemistry
Inorganic chemistry
Chemistry
double carbonylation
Selectivity

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