Crack Initiation and Propagation Under Hydrogen-Enhanced Fatigue of a Cr-Mo Steel for Gaseous Hydrogen Storage

The current international standards and codes dedicated to the design of pressure vessels do not properly ensure fitness for service of such vessel used for gaseous hydrogen storage and subjected to hydrogen enhanced fatigue. Yet, hydrogen can reduce the fatigue life in two ways: by decreasing the crack initiation period and by increasing the fatigue crack growth rate. The European project MATHRYCE aims are to propose an easy to implement vessel design methodology based on lab-scale tests and taking into account hydrogen enhanced fatigue.The study is focused on a low alloy Cr-Mo steel, exhibiting a tempered bainitic and martensitic microstructure, and classically used to store hydrogen gas up to 45 MPa. Due to hydrogen diffusion at room temperature in such steel, tests have to be performed under hydrogen pressure to avoid outgassing.In the present work, experimental procedures have been developed to study both crack initiation and crack growth. The specimens and tests instrumentation have been specifically designed to quantitatively measure in-situ these two stages under high hydrogen pressure. We developed and tested crack gages located close to a small drilled notch. This notch simulates the presence of steel nonmetallic inclusions and other microstructural features that can affect fatigue crack initiation and propagation. The experimental results addressing the effects of the testing conditions, such as stress ratio, frequency and hydrogen pressure will be compared to the local strain and stress fields obtained by Finite Element Method and correlated to the possible hydrogen enhanced fatigue mechanisms involved.Copyright © 2014 by ASME