Реокинетические особенности процесса отверждения олигодиенуретанового форполимера гидроксилсодержащим отвердителем
2012
For the first time identified features reokinetic curing prepolymer polydienurethan brand «Krasol NN23» glycerin and it is shown that this process is a multistage, because of the different functional reactants. Revealed that up to the point of the structure formation occurs miсrogel homogeneously in the kinetic region to respond, and after reaching a point mikrogel heterogeneously in the diffusion region. The values of rate constants of the process of structure formation have been proposed kinetic models for limiting step curing.
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