Zeolites fit for a crown: Studying organic-framework host-guest interactions through thermogravimetric techniques

Abstract Every year millions of tons of zeolites are produced, being used as molecular sieves, hydrocracking catalysts, gas-capture materials and for emerging novel applications. There is a demand to synthesise new zeolites with bespoke frameworks, which are tailor-made for a chosen application. To achieve these ‘designer zeolites’ it is crucial to fully understand the host-guest interactions between organic additives and zeolitic frameworks. Here we have studied four different zeolites, synthesised with the same organic additive, 18-crown-6 ether, which show observable differences in the host-guest interactions. We demonstrate that the framework geometry dominates the decomposition temperature, enthalpy and mechanism. The zeolites show unique decomposition features, emphasising experimental differences in how the organic additive and framework interact.