Optical Behaviour of Carbon Dot:Spectral, Dynamical and Structural Aspects
2018
Photoluminescent carbon dots (CDs) represent an exciting new class of oxygen containing
carbonaceous emitters. Serendipitous discovery of carbon dot as a by-product of single
walled carbon nanotube purification has triggered extensive studies to explore fluorescence
properties of CDs. Since then various synthetic methods have been developed to produce
highly luminescent CDs. Previously reported CDs were of low photoluminescence quantum
yield (PLQY) and the composition of these CDs was not known. Most of the CDs exhibit
either excitation dependent emission and /or multiexponential decay behaviour. Thus, the
first challenge was to understand the molecular origin of photoluminescence of CD. There is
ambiguity regarding the location of fluorescing moiety in CD. Some researchers have
surmised that the fluorescing unit is at the surface, whereas, some researchers have
mentioned that the fluorescing unit is inside CD. However, there is no direct evidence
regarding the location of fluorescing unit. Hence, it is necessary to investigate the exact
location of fluorescing unit in CD. In order to utilise the CD for bioimaging it was necessary
to increase the PLQY of CD in aqueous medium. Most of the carbon based nanomaterials
have been shown to act as fluorescence quencher. Thus, to increase applicability of the CD it
was necessary to show that CD does not act as a fluorescence quencher. It would be better if
it is possible to show that CD can act as fluorescence donor especially in resonance energy
transfer (RET) based experiment. For many nanomaterials it has been shown that Forster
model of RET cannot explain the experimental observables of RET. It was thus necessary to
check whether the vastly applied Forster model can be useful to understand the RET
phenomenon involving CD. Previously reported CDs have been shown to exhibit
multiexponential PL decay, however, fluorescence dynamical analyses becomes much easier
if the PL decay is single exponential. Moreover, multiexponential PL decay rises concern
about the origin of different decay channels. Those problems can be alleviated if the PL
decay is single exponential.
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