Efficient Construction of Near-Infrared Absorption Donor–Acceptor Copolymers with and without Pt(II)-Incorporation toward Broadband Nonlinear Optical Materials
2020
Organic nonlinear optical (NLO) materials have attracted immense scientific interest in various fields. Broadband NLO response extending to near-infrared (NIR) region is extremely important and remains challenging. Herein, two diketopyrrolopyrrole (DPP)-based donor–acceptor (D–A)-type π-conjugated copolymers with and without Pt(II) incorporation are rationally designed and synthesized toward broadband NLO response materials. The broad intramolecular charge transfer (ICT) absorption reaching 1000 nm due to the strong D–A interaction is well demonstrated by photophysical characterizations. The NLO properties of copolymers are studied using Z-scan technology. Owing to their extended π-conjugated D–A systems and near-infrared ICT absorption properties, both copolymers exhibit laser-induced NLO response to nanosecond as well as picosecond laser pulses upon the wavelengths of 532 and 1064 nm. Interestingly, introducing Pt(II) into the copolymer backbone can evidently improve the NLO property or unexpectedly swi...
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