Synthesis and Characterization of the Diruthenium(III) Complexes Ru2(F4Oap)2(F5ap)2 and Ru2(F4Oap)(F4NCNap)(F5ap)2 Where F4Oap Is the 2-(3,4,5,6-Tetrafluoro-2-oxoanilino)pyri- dinate Anion, F4NCNap Is the 2-(3,4,5,6-Tetra- fluoro-2-cyanamidoanilino)pyridinate Anion, and F5ap Is the 2-(2,3,4,5,6-Pentafluoroanilino)pyri- dinate Anion

John L. Bear,Yulan Li,Baocheng Han,and Eric Van Caemelbecke,Karl M. Kadish

Synthesis and Characterization of the Diruthenium(III) Complexes Ru2(F4Oap)2(F5ap)2 and Ru2(F4Oap)(F4NCNap)(F5ap)2 Where F4Oap Is the 2-(3,4,5,6-Tetrafluoro-2-oxoanilino)pyri- dinate Anion, F4NCNap Is the 2-(3,4,5,6-Tetra- fluoro-2-cyanamidoanilino)pyridinate Anion, and F5ap Is the 2-(2,3,4,5,6-Pentafluoroanilino)pyri- dinate Anion

2001

John L. Bear
Yulan Li
Baocheng Han
and Eric Van Caemelbecke
Karl M. Kadish

Two diruthenium(III) complexes with mixed anionic bridging ligands are synthesized and characterized as to their structural, electrochemical, and spectroscopic properties. Both compounds undergo not only metal-centered but also ligand-centered electrode reactions and this is accounted for by their quinone-type structures.

Keywords:

Inorganic chemistry
Ion
Ligand
Chemistry
Electrode
Electrochemistry
Photochemistry
Polymer chemistry

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