Solid-State NMR Studies of Mesostructured Alumino-Phosphates: Structure and Dynamics of the Inorganic Network and of the Organic Component

An array of solid-state NMR techniques has been used to characterise alumino- phosphates with hexagonal and lamellar mesostructures. Differences between the mesocomposites regarding the inorganic component, state of the template and arrangement of the inorganic/organic interface have been identified. We describe the complex picture of the structure of the hybrid solids.