Silver-Modified β-Cyclodextrin Polymer for Water Treatment: A Balanced Adsorption and Antibacterial Performance

Water pollution caused by organic pollutants and pathogenic microorganism is a critical issue. In this study, we reported a silver-modified β-cyclodextrin polymer (CD-CA/PDA-Ag) used for the removal of dyes and the suppression of microorganisms from water. In order to avoid silver nanoparticles agglomeration, the material was first coated with polydopamine (PDA) on β-cyclodextrin matrix, whose reducing catechol groups subsequently immobilized silver ions in situ to form uniformly dispersed silver nanoparticles. CD-CA/PDA-0.5Ag displayed a high adsorption capacity of methylene blue (535.93 mg/g), which is mainly attributed to electrostatic interactions, host-guest inclusions and π-π bond stacking effects. Furthermore, both diffusion inhibition zone tests and colony formation unit tests were investigated, which showed excellent antimicrobial capability on Escherichia coli (E. coli) and Staphylococcus aureus (S. auerus). Overall, CD-CA/PDA-Ag proved to have an excellent adsorption capacity and antibacterial performance, which provides a great potential in water purification.