Synthesis of Aromatic Anion Exchange Membranes by Friedel–Crafts Bromoalkylation and Cross-Linking of Polystyrene Block Copolymers

Elastomeric anion exchange membranes (AEMs) were prepared by acid-catalyzed Friedel–Crafts alkylation of the polystyrene block of polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene (SEBS) using bromoalkylated tertiary alcohols and triflic acid as a catalyst, followed by amination with trimethylamine. This simple one-step bromoalkylation allowed convenient control of both the degree of functionalization and cation tether length by changing the molar ratio and the structure of the bromoalkylated tertiary alcohol. The resulting quaternary ammonium-functionalized ionic triblock SEBS copolymers showed a microphase-separated morphology on the 35 nm length scale. A series of AEMs with different ion exchange capacities and ion tether lengths were systematically investigated by comparing swelling and anion conductivity. Because the SEBS AEMs showed high swelling and low dimensional stability in water due to the rubbery nature of SEBS, the hard segment PS units were cross-linked by 1,6-hexanediamine for practic...