A wide temperature tolerance, solution-processed MoOx interface layer for efficient and stable organic solar cells

2017 
Abstract While solution processable MoO x films (S-MoO x ) are typically sensitive to thermal treatment temperature and oxygen, we report an approach with the features of a wide temperature tolerance, water-free and solution-processed S-MoO x film for organic solar cells (OSCs), The structural, morphological, electronic properties of synthesized S-MoO x film were studied in detail by using field emission scanning electron microscopy (SEM), Contact angle meter, UV–visible Spectrophotometer (UV–vis), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and scanning kelvin probe force microscopy (SKPFM). These analysis shows that the S-MoO x thin films possess the suitable morphology and electronic properties for application in OSCs. The S-MoO x film shows wide temperature tolerance from room temperature to 250 °C. The S-MoO x was introduced into OSCs in normal and inverted configuration by acting as anode interface layer. The devices shows relatively high performance (ca 7.40%) based on varying temperature treated S-MoO x . The stability of the OSCs is dramatically enhanced via using the S-MoO x layers replace the conventional PEDOT:PSS layer both in air and in nitrogen atmosphere.
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