Syntheses of [60]Fullerene and N,N-Bis(4-biphenyl)aniline-Tethered Rotaxane: Photoinduced Electron-Transfer Processes via Singlet and Triplet States of [60]Fullerene

A rotaxane containing [60]fullerene (C 6 0 ) and N,N-bis(4-biphenyl)aniline (BBA) moieties was synthesized. In this structure, C 6 0 acting as an electron acceptor, is attached to the crown-ether ring through which the axle with terminal BBA moieties acting as electron donors on both ends is penetrating. This rotaxane had a neutral amide moiety in the center of the axle in which two BBA moieties act as stoppers. The intra-rotaxane photoinduced electron-transfer processes of the C 6 0 and BBA moieties were investigated by time-resolved transient absorption and fluorescence measurements while changing solvent polarity and temperature. Time-resolved transient absorption measurements of the rotaxanes confirmed that the long-lived charge-separated state (C 6 0 . - ; BBA . + ) r o t a x a n e was formed via both the excited singlet and triplet states of C 6 0 ( 1 C 6 0 * and 3 C 6 0 *, respectively) in polar solvents. The rate constants for charge-separation process were evaluated to be in the range of (3.6-3.7) x 10 8 s - 1 via 1 C 6 0 * and (5.1-5.6) x 10 7 s - 1 via 3 C 6 0 * in the ratio of (0.36-0.38):(0.43-0.51). The rate constants of charge recombination were 2.5 x 10 6 s - 1 and 4.4 x 10 6 s - 1 , corresponding to the lifetimes of the charge-separated states of 400 ns and 230 ns in THF and benzonitrile, respectively. By the temperature dependences, the activation free-energy changes of charge-separation process via 3 C 6 0 * were evaluated to be 0.10 eV, while those of the charge-recombination process were estimated to be 0.03 eV in THF and benzonitrile. These low activation energies are one of the characteristics of through-space electron transfer in the rotaxanes.