Fabrication and optical properties of C/β-SiC/Si hybrid rolled-up microtubes

C/β-SiC/Si hybrid microtubes have been fabricated by releasing prestressed C/Si bilayer structures and treating with a postannealing process. Detailed characterization reveals the synthesis of β-SiC via a solid phase reaction at the C/Si interface. Remarkably, the production of β-SiC is promoted in the tube wall by rolled-up bonding of adjacent windings, which increases the area of the C/Si interface by a factor of 2. The Raman spectra acquired from the hybrid microtubes disclose peaks pertaining to the optical phonon modes of β-SiC that exhibit obvious downshifts due to surface effects on the SiC nanoparticles. Moreover, two light emission bands are detected from a hybrid microtube and their origin is discussed based on spectral analyses.