Occurrence of well-crystallized nontronite in the gas vesicles of a megaporphyritic basalt flow near Nighoj, Ahmednagar district, Maharashtra

Occurrence of well crystallized nontronite in a megaporphyritic basalt flow from Nighoj area, Maharashtra, India is reported. Thin section studies of the vesicles from periphery to the centre reveal the presence of greenish palagonite, probably indicating the stages of devitrification of glass and the weathering of palagonite to the formation of nontronite. The centre of the vesicles is marked by the presence of dark greenish-brown, radiating and fibrous sheets of nontronite. X-ray diffraction (XRD) analysis reveals the dominant presence of smectite (nontronite) as the major phase with traces of pyroxene. Scanning Electron Microscopy (SEM) shows well developed sheets of nontronite within the gas vesicles of the megaporphyritic basalt flows. In the present investigation, the nontronite within the gas vesicles of the megaporphyritic basalts at Nighoj was formed in-situ due to the devitrification of glass containing palagonite. Palagonite is an intermediate step in the alteration that may be accomplished by the steam generated in quenching of the lava. Weathering of palagonite under conditions of poor drainage is essential to the genesis of nontronite as has been suggested by Victor and Vernon (1946).