(E)-2,4-Dibromo-6-(hydrazinylidenemethyl)phenol
2017
The title compound, C7H6Br2N2O, was obtained from a condensation reaction of 3,5-dibromo-2-hydroxybenzaldehyde and hydrazine hydrate. The molecule is approximately planar, the largest deviation from the mean plane through all of the non-H atoms being 0.053 (1) A. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond, generating an S(6) ring motif. In the crystal, intermolecular N—H⋯Br and N—H⋯O hydrogen bonds link the molecules, forming chains parallel to the b axis. Molecules are further linked by π–π stacking interactions, with centroid–centroid distances of 3.925 (3)–3.926 (3) A, forming a three-dimensional network.
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