Preparation and characterization of core-shell structured LiFePO4/C composite using a novel carbon source for lithium-ion battery cathode

Abstract Core-shell structured LiFePO 4 /C 1 cathode material is synthesized via a rapid microwave irradiation route using ethylene diamine tetraacetic acid (EDTA) as the novel carbon source. XRD results reveal that all the patterns can be indexed as the olivine-type structured LiFePO 4 with the space group of Pnma . TEM images show that the obtained carbon is an amorphous layer with a thickness of about 3–4 nm. When the LiFePO 4 /C 1 used as cathode material for lithium-ion battery, it delivers an initial discharge capacity of 163.1 mAh g −1 at 0.1 C which is about 96% of the theoretical capacity. Moreover, it also shows excellent rate performance and good cycle stability due to the enhanced electronic conductivity as proved by the electrochemical impedance spectroscopy (EIS). Thus, this carbon decorated LiFePO 4 composite synthesized via the rapid microwave irradiation method is a promising cathode material for high-performance lithium-ion battery.