Phytoalexins from hairy roots of Hyoscyamus albus treated with methyl jasmonate
1998
The treatment of hairy roots of Hyoscyamus albus with copper sulfate (Cu 2+ ) and methyljasmonate (JAMe) produced several phytoalexins having the vetispyrane skeleton. Lubimin and solavetivone were isolated after treatment with Cu 2+ . Seven sesquiterpenoid phytoalexins were isolated from the culture medium after treatment with JAMe, including lubimin, solavetivone, 3-hydroxysolavetivone and four new compounds (1-4). Structures of the new compounds were elucidated to be (3R,4S,5R,7S,9R))-3-hydroxy-9-tigloyloxysolavetivone (1), (3R,4S,5R,7S, 9R)-3-hydroxy-9-(3-methylbutenoyloxy)-solavetivone (2), (3R,4S, 5R, 7S,9R)-3-hydroxy-9-isobutanoyloxysolavetivone (3); and (3R,4S, 5R, 7S,9R)-3,9-dihydroxyso-lavetivone (4). The induction pattern of phytoalexins in hairy roots treated with JAMe was different in those treated with Cu 2+ , and co-treatment with JAMe and Cu 2+ gave only solavetivone.
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