Milling method for synthesizing metal mercapto thiazole compound

The present invention discloses a formula (the I), milling synthesis method, a metal compound of a mercapto thiazoles of formula (II) shown as follows: in a ball mill was added 2-amino-5-mercapto-reactor 1,3 , 4-thiadiazole or thiazole-2-mercaptobenzothiazole, was added spheres, metal salts, and a solvent, reaction was ball milled, tracking and monitoring TLC, after completion of the reaction, the reaction mixture was treated, was added 2-amino-5-mercapto -1,3,4-thiadiazole to give compound of formula (I) represented by; adding the compound 2-mercaptobenzothiazole obtained thiazol of formula (II) shown; synthesis of mercapto thiazoles metal compound provided by the present invention process is simple, substantially no waste, good product purity, high yield and is suitable for industrial application;