Synthesis of dihydrosilanaphthoindolizines and dihydrosilaazaaceanthrelenes
1981
Abstract New heterocyclic systems, dihydrosilanaphthoindolizines and dihydrosilaazaaceanthrelenes, have been synthesized starting from 9,10-dihydro-9-sila-3-azaanthracenes. Substituted 6,11-dihydro-6-silanaphtho[2,3- g ]indolizines were obtained as a result of 1,3-dipolar cycloaddition reaction of dimethylacetylenedicarboxylate with the quaternary salts of dihydrosilaazaanthracenes having a N -phenacyl group. In a similar manner, substituted 3 H ,6 H -6-sila-3-azaaceanthrelenes, a new pseudoazulene system, have been synthesized from N -benzyl (methyl) quaternary salts. Dihydrosilanaphthoindolizine, having a linear linkage of the dihydrosilanaphtholene and the indolizine cycles has been synthesized from the corresponding dihydrosilaazaanthracene quaternary salt using the Tschitschibabin method.
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