Gold-Containing Catalysts Based on Mesoporous Metal–Organic Frameworks of the MIL Type for Regioselective Hydroamination Reaction of Phenylacetylene

Catalyst systems based on gold nanoparticles introduced into the matrices of mesoporous metal–organic frameworks of the MIL type based on trivalent metal ions (Al, Fe) manifest activity in the regioselective hydroamination of phenylacetylene with aniline according to the Markovnikov rule. The activity of the synthesized gold-containing systems significantly depends on the nature of organic and inorganic building units, metal ions, and organic linkers, which form the framework, as well as on the catalyst preparation procedure.