New Synthesis of Pinacols by Oxidative Coupling Mediated by 1,2-Disulfides as Dehydrogenating Reagents under Irradiation.

Hidehiko Fujisawa,Yuichiro Hayakawa,Yasuhiro Sasaki,Teruaki Mukaiyama

New Synthesis of Pinacols by Oxidative Coupling Mediated by 1,2-Disulfides as Dehydrogenating Reagents under Irradiation.

2001

Hidehiko Fujisawa
Yuichiro Hayakawa
Yasuhiro Sasaki
Teruaki Mukaiyama

A new procedure for the synthesis of pinacols is established by way of oxidative coupling reaction of benzylethers with a thiyl radical, a hydrogen acceptor, generated from disulfide under UV irradiation.

Keywords:

Irradiation
Oxidative coupling of methane
Photochemistry
Chemistry
Reagent
Organic chemistry

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