Oxidation of Allylic Alcohols by Dimethyldioxirane: Competition Reaction Between Epoxidation and C-H Insertion.
2010
Abstract Epoxidation of allylic alcohols with dimethyldioxirane is accompanied by oxidation of the hydroxy functionality; thus enone formation increases with decreasing substitution at the CC double bond; nonetheless, selective epoxidation can be obtained by acylation of the alcohol functionality.
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