Samarium–neodymium chronology and rubidium–strontium systematics of an Allende calcium–aluminum-rich inclusion with implications for 146Sm half-life

Calcium–aluminum-rich inclusions (CAIs) are primitive objects that formed within the protoplanetary disk surrounding the young Sun. Recent Pb–Pb chronologic studies have demonstrated that CAIs are the oldest solar system solids, crystallizing 4567 Ma ago (Amelin et al., 2002 ;  Connelly et al., 2012). The isotope systematics of CAIs therefore provide critical insight into the earliest history of the Solar System. Although Sm–Nd and Rb–Sr geochronometers are highly effective tools for investigating cosmochemical evolution in the early Solar System, previous studies of CAIs have revealed evidence for isotopically disturbed systems. Here we report new age data for Allende CAI Al3S4 derived from both the long-lived (147Sm–143Nd) and short-lived (146Sm–142Nd) isotopic systems. The 147Sm–143Nd chronometer yields an age of 4560±34 Ma4560±34 Ma that is concordant with 207Pb–206Pb ages for CAIs and indicates that the Sm–Nd system was not significantly disturbed by secondary alteration or nucleosynthetic processes. The slope of the 146Sm–142Nd isochron defines the Solar System initial 146Sm/144Sm of 0.00828±0.000440.00828±0.00044. This value is significantly different from the value of 0.0094 determined by Kinoshita et al. (2012). Ages recalculated from all published 146Sm–142Nd isochron data using the traditional 103 Ma half-life and the initial 146Sm/144Sm value determined here closely match Pb–Pb and 147Sm–143Nd ages determined on the same samples. In contrast, ages recalculated using the 68 Ma half-life determined by Kinoshita et al. (2012) and either of the initial 146Sm/144Sm values are often anomalously old. This is particularly true for the youngest samples with 146Sm–142Nd isochron ages that are most sensitive to the choice of 146Sm half-life used in the age calculation. In contrast to the Sm–Nd isotope system, the Rb–Sr system is affected by alteration but yields an apparent isochron with a slope corresponding to a much younger age of 4247±110 Ma4247±110 Ma. Although the Rb–Sr system in CAIs appears to be disturbed, the initial 87Sr/86Sr value determined from the isochron is 0.698942±0.0000080.698942±0.000008, and closely approximates estimates of the initial Solar System value. Although this isochron may be a mixing line, it might also record alteration on the Allende parent body in which Rb was added to the Al3S4 CAI that was initially largely devoid of Rb.