I2–DMSO catalyzed synthesis of 1,2,2-triarylethanones via dual C–H activation of aryl methyl ketones
2014
Abstract An I 2 –DMSO promoted domino protocol was developed for the synthesis of 1,2,2-triarylethanones from readily available aromatic methyl ketones and methoxybenzenes. The 1,2,2-triarylethanones are important precursors for the synthesis of Tamoxifen and Droloxifene. The use of mild reaction conditions, high yield, and single step synthesis are the advantages of the present protocol.
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