The nitrogen-15 n.m.r. criterion of bond angle in nitrosyl complexes

L Bell,D. Michael P. Mingos,David G. Tew,Leslie F. Larkworthy,Barry Sandell,David C. Povey,Joan Mason

The nitrogen-15 n.m.r. criterion of bond angle in nitrosyl complexes

1983

L Bell
D. Michael P. Mingos
David G. Tew
Leslie F. Larkworthy
Barry Sandell
David C. Povey
Joan Mason

Deshielding of 350–700 p.p.m. is reported for nitrogen in strongly bent nitrosyl groups (∠MNO ca. 120°) in complexes of Rh or Co, compared with linear nitrosyl groups in complexes of Fe, Co, Ru, and other transition metals.

Keywords:

Inorganic chemistry
Nitrogen
Transition metal
Chemistry
Molecular geometry
Bent molecular geometry
Organic chemistry
Photochemistry

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