Copper(II)-Catalyzed Aminooxygenation and Carboamination of N-Aryl-2-allylanilines

The scope of the intramolecular copper(II)-catalyzed carboamination and aminooxygenation reactions of olefins has been extended to include N-aryl-2-allylanilines. These substrates exhibit divergent reactivity under catalytic vs. stoichiometric conditions.