An iterative divergent approach to conjugated starburst borane dendrimers
2020
: Using a new divergent approach, conjugated triarylborane dendrimers were synthesized up to the 2 nd generation. The synthetic strategy consists of three steps: 1) functionalization, via iridium catalyzed C-H borylation; 2) activation, via fluorination of the generated boronate ester with K[HF 2 ] or [N( n Bu 4 )][HF 2 ] ; and 3) expansion, via reaction of the trifluoroborate salts with aryl Grignard reagents. The concept was also shown to be viable for a convergent approach. All but one of the conjugated borane dendrimers exhibit multiple, distinct and reversible reduction potentials, making them potentially interesting materials for applications in molecular accumulators. Based on their photophysical properties, the 1 st generation dendrimers exhibit good conjugation over the whole system. However, the conjugation does not further increase upon expansion to the 2 nd generation, but the molar extinction coefficients increase linearly with the number of triarylborane sub-units, suggesting a potential application as photonic antennas.
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