Characterization of Unsaturated Hydraulic Conductivity in Fractured Media Using the Multistep Outflow Method - 15461

The multistep outflow method is routinely used to characterize the unsaturated hydraulic conductivity of soils. The technique involves placing a soil sample in a pressure plate apparatus, subjecting the sample to multiple gas pressures in discrete steps through time, and measuring the transient volume of pore fluid extracted. Unsaturated hydraulic property values are estimated through inverse modeling of the experimental conditions. In this study the multistep outflow concept was applied to micro-cracked cementitious materials to assess the efficacy of the technique for these materials. The cementitious materials tested were salt-waste simulant grout samples artificially damaged through oven-drying. Compared to typical soils, fractured media exhibit higher saturated conductivity and lower air-entry pressure, and the volume of fluid extractable from fractures is much lower than soil porosity. To accommodate these material differences the standard test apparatus was modified to incorporate a higher conductivity ceramic pressure plate, a high-precision digital balance for logging outflow mass, a low volume (diameter) effluent line, multiple inline high-precision gas regulators, and a high-precision low-range pressure gauge. Testing to date indicates that the modified apparatus can provide a viable means to measure the unsaturated hydraulic properties of micro-fractured cementitious materials. However the accuracy/uniqueness of inverse modeling is limited by the inherent characteristics of fractured media: high saturated conductivity, low air-entry pressure, and strong non-linearities. Hydraulic property results in the form of van Genuchten / Mualem curves are presented for three fractured grout specimens. DOE Performance Assessments often involve cementitious barriers and/or waste forms that are predicted or assumed to degrade over time due to various mechanisms such as carbonation-influenced reinforcing steel corrosion, external sulfate attack, differential settlement, and seismic activity. Physical degradation typically takes the form of small-scale cracking / fracturing, and the affected materials reside in unsaturated hydrogeologic zones. In these cases, unsaturated hydraulic properties are needed for fractured cementitious materials to simulate moisture movement and contaminant transport within and around the facility. The outflow extraction method, as implemented in the present study, provides a suitable method for estimating these material properties.