Redox Switching of Conjugation Length Using 9,9,10,10-Tetraaryl-9,10-dihydrophenanthrene as an ON/OFF Unit: Preparation, X-ray Structure, and Redox Properties of Perfluorobiphenyl Derivative and Its SNAr Reactions to π-Extended Analogues

Takanori Suzuki,Hitomi Tamaoki,Ryo Katoono,Kenshu Fujiwara,Junji Ichikawa,Takanori Fukushima

Redox Switching of Conjugation Length Using 9,9,10,10-Tetraaryl-9,10-dihydrophenanthrene as an ON/OFF Unit: Preparation, X-ray Structure, and Redox Properties of Perfluorobiphenyl Derivative and Its SNAr Reactions to π-Extended Analogues

2013

Takanori Suzuki
Hitomi Tamaoki
Ryo Katoono
Kenshu Fujiwara
Junji Ichikawa
Takanori Fukushima

Octafluorobiphenyl-2,2′-diylbis(diarylmethylium) dye 2a2+ prepared from 1,2-dibromotetrafluorobenzene is interconvertible with colorless dihydrophenanthrene donor 1a. By the SNAr reactions of 1a wi...

Keywords:

Redox
Nucleophilic aromatic substitution
Inorganic chemistry
Organic chemistry
Chemistry
Photochemistry
X-ray

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