Surfacing With Tungsten-containing Ores

Experimental research has been carried out into AN 26C flux surfacing with flux cored wires made of dust-like carbon and fluorine containing components and tungsten- containing ores. The investigations have revealed the fact that tungsten can be reduced immediately from tungsten-containing oxide materials. The chemical composition of added metal has been determined, as well as slag compositions after surfacing; hardness, wear resistance have been investigated and metallographic tests have been carried out. Thermodynamic calculations of reactions of WO3, as well as W2C and WC carbides reduction to W by carbon and carbon oxide have been made in standard conditions at temperature T = 1500 - 6000 K. The obtained thermodynamic characteristics of reactions have demonstrated that in the course of WO3 reduction tungsten is most likely to be obtained in terms of thermodynamics, subsequently W2C and WC carbides. After these reactions those of W2C and WC carbides obtaining are thermodynamically possible via reduced tungsten and carbon composition.