Interesting polarization-independent SERS detection performance induced by the rotation symmetry of multiparticle nanostructures.

In this work, on the basis of finite difference time domain simulations and group theory, by employing regular nanosphere trimers as the main examples, we analyse and discuss the polarization-independent surface enhanced Raman scattering (SERS) phenomenon arising from the rotation symmetry of coined metallic nanomultimers. The results demonstrate why the rotationally symmetrical nanomultimers can show polarization-independent SERS performance. Because of the dramatically hybridized polarization-independent SERS performance over the whole 360° range, rotationally symmetrical coined metal nanomultimers, such as regular trimers, regular triangular tetramers and regular pentamers, are reliable and reproducible SERS substrates, which have the potential for convenient and flexible practical SERS detection without the need for optimally incident polarization outside the laboratory setting.