Structure of the smectic D phase

Abstract The so-called ‘smectic’ D phase of 4′-n-octadecyloxy-3′-cyanobiphenyl-4-carboxylic acid (one of only four materials known to exhibit this phase) has been shown unambiguously by X-ray diffraction to be characterized by a primitive cubic space group. The space group is either P23 or Pm3, and the lattice parameter a 0 is 86 A. It is shown that data from previous studies of this phase may be re-intepreted to be consistent with these findings. In view of these conclusions it is clearly inappropriate to refer to the phase as smectic.