Effect of hydration on conformational change or stabilization of (1 .fwdarw. 3)-.beta.-D-glucans of various chain lengths in the solid state as studied by high-resolution solid-state carbon-13 NMR spectroscopy
1989
L'effet de l'hydratation depend fortement de la conformation des glucanes etudies: la forme hydratee des glucanes a MW elevee (cureltan, pachyman) adopte une conformation en helice simple identique a celle du gel elastique; l'hydratation du cureltan recuit ne change pas le spectre. L'hydratation du paramylon en helice triple provoque un retrecissement des signaux RMN 13 C
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