Pd-catalyzed couplings of (α-fluoro)vinyl tris(trimethylsilyl)germanes
2005
The (α-fluoro)vinyl tris(trimethylsilyl)germanes undergo Pd-catalyzed cross-couplings with aryl and alkenyl halides upon oxidative treatment with hydrogen peroxide under basic aqueous conditions to give access to fluoroalkenes and fluorodienes with retention of stereochemistry.
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