Water-insoluble aerogels made from cellulose nanocrystals and poly(vinyl alcohol)

Cellulose nanocrystal (CNC) aerogels are attractive low-density materials, although the brittleness and/or water dispersibility can limit the usefulness of these materials. The authors report here the preparation of water-insoluble aerogels made by lyophilization of aqueous dispersions of low-aspect ratio CNCs extracted from cotton. Poly(vinyl alcohol) (PVOH) was added as a polymeric binder, and the PVOH- and the CNC-concentration ([PVOH] and [CNC]) as well as the freeze-drying conditions were systematically varied. The effect of these parameters on the morphology, mechanical properties and the specific surface area of the resulting CNC/PVOH aerogels was investigated. By increasing the PVOH-concentration, the stiffness of the aerogels increases by a factor of two, and varying the [CNC] as well as the freezing method leads to different pore morphologies. An environmentally friendly, isothermal annealing process was used to induce crosslinking without the need for auxiliary chemicals and was shown to decrea...