Structure of the indium-rich InSb(001) surface
2010
The indium-rich InSb(001) surface, that shows the $c(8\ifmmode\times\else\texttimes\fi{}2)$ reconstruction at room temperature and a partially disordered phase at 77 K (the low temperature or LT phase), is studied experimentally by means of scanning probe microscopies, low-energy electron diffraction, and angle-resolved photoelectron spectroscopy (ARPES), as well as theoretically, using the density-functional theory (DFT). The experimental studies are done both at room temperature and at cryogenic temperatures. No metallic surface bands are found using ARPES, consequently the idea of charge-density waves as a possible explanation of the LT phase suggested previously by Goryl et al. [Surf. Sci. 601, 3605 (2007)] is discarded. On the other hand it is shown that an essential core of the surface structure is described by the so-called $\ensuremath{\zeta}$ model which has the $c(8\ifmmode\times\else\texttimes\fi{}2)$ symmetry. However, on top of this basic structure there are additional not fully occupied indium-atom rows. Vacancies/atoms in these rows rapidly fluctuate at room temperature while, upon cooling down, they stabilize to form a sublattice also of $c(8\ifmmode\times\else\texttimes\fi{}2)$ symmetry. Furthermore, this sublattice has shifted mirror symmetry axes (relating to those of the underlying $\ensuremath{\zeta}$ lattice) therefore the surface symmetry is lowered from $c2mm$ to $p2$ and structural domains are formed. This occurs with no significant core $\ensuremath{\zeta}$ lattice distortions but dense domain borders lead to significant disorder in the top atomic layer. DFT calculations confirm that the postulated $\ensuremath{\zeta}$-like structure with additional 50% occupied indium-atom rows is stable on the InSb (001) surface. Calculated, in the Tersoff-Hammann approximation, scanning tunneling microscopy (STM) images of the relaxed surface structure agree well with experimental STM images.
Keywords:
- Conductive atomic force microscopy
- Vibrational analysis with scanning probe microscopy
- Surface reconstruction
- Indium
- Scanning capacitance microscopy
- Low-energy electron diffraction
- Nuclear magnetic resonance
- Photoconductive atomic force microscopy
- Inorganic chemistry
- Physics
- Kelvin probe force microscope
- Non-contact atomic force microscopy
- Optoelectronics
- Spin polarized scanning tunneling microscopy
- Scanning tunneling spectroscopy
- Condensed matter physics
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
0
References
14
Citations
NaN
KQI