Ligand-Field Energy Splitting in Lanthanide-Based Single-Molecule Magnets by NMR Spectroscopy

A method for the experimental determination of ligand-field (LF) energy splitting in mononuclear lanthanide complexes, based purely on variable-temperature NMR spectroscopy, was developed. The application of this method in an isostructural series of anionic lanthanide bis(cyclooctatetraenide) double-decker compounds bearing large rigid substituents is demonstrated. Using the three-nuclei plot approach devised by Reilley, the isostructurality of the compound series and the identical orientation of the magnetic main axis of all Ln3+ ions in the series Tb3+ to Tm3+ are demonstrated. Measurement of the 2H NMR spectra of partially deuterated analogues of the complexes permitted determination of the axial magnetic susceptibility anisotropies χax for all five ions in the temperature range from 185 to 335 K. For this purpose, analysis of the hyperfine shifts was combined with structural models derived from density functional theory calculations. In a final step, the temperature dependence of the χax values was us...