Online analysis of gas-phase radical reactions using vacuum ultraviolet lamp photoionization and time-of-flight mass spectrometry

A home-made vacuum ultraviolet photoionization time-of-flight mass spectrometer has been developed and coupled to an atmospheric simulation chamber operated at atmospheric pressure and to a fast flow tube at low pressure (1–10 Torr). Gas sampling from the simulation chamber is realized directly via a capillary effusive beam, and sampling from the flow tube is via a continuous molecular beam inlet. Both devices are connected simultaneously to the ionization chamber of the mass spectrometer and can be switched in-between within minutes to study gas-phase radical reactions of atmospheric interest in a large range of reaction conditions and reaction times (from milliseconds in the flow tube to hours in the simulation chamber). A cage-shaped photoionization source combined with a commercial 10.6 eV krypton lamp has been developed to provide a high ion collection efficiency along the long light path in the cage. This way, a multiplexed detection with high sensitivity down to the sub-parts per billion volume con...